One thing that I forgot to mention is beneficiary on life insurance or RRSP's. You will want to switch this over probably to pay out to your children, or name a trustee for them. Also change your will, or write a will if you don't have one.
These are all important details on their own, but again, you want documentation to show that you intentionally separated from him on a certain date because he is going to dispute you.
(I'd suggest his motive is that he doesn't want to pay you child support for the kids, that's probably pretty obvious.)
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